Thanks folks. It is addictive watching the Victron VRM site and seeing what's going on
Annoyingly, we are shaded by a large block of flats and industrial buildings until around midday, if the sun comes out! But we do have over 10kWp installed, so I look forward to white high cloud mornings, as we get more generation than if it was blue sky until the sun comes over the buildings.
I woke up this morning and saw we had a 'phase' down on the main distro panel
But then remembered that's because the Quattro was still programmed for the old batteries to cut the power to the electric shower when SOC hits 50%, so will need to re-programme the assistants and reboot.
Currently it looks like the internal BMS's thinks we're at 43% SOC and the SmartShunt says 48.9%

I believe the SmartShunt more, but it is only the first discharge cycle, so the BMS's may need to sync to the cells still.